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العنوان
The Direct Introduction of Diazonium Group into Aromatic Heterocyclic Moieties and Preparation of some Derivatives Therefrom /
المؤلف
Abd El-Monem, Maisa Esmeil.
هيئة الاعداد
باحث / مايسة اسماعيل عبد المنعم
مشرف / سعود عبد المنعم محمد
مناقش / فتحى عبد القادر
مناقش / عبد الماجد امين
الموضوع
Organic compounds.
تاريخ النشر
1986.
عدد الصفحات
146 P. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Organic Chemistry
الناشر
تاريخ الإجازة
11/1/1987
مكان الإجازة
جامعة أسيوط - كلية العلوم - Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

The work described in this thesis is concerned with the application of the reaction established by J.M. Tedder in 1957 which deals with the direct introduction of diazoonium group in aromatic nuclei. Tedder applied this reaction to some activated aromatic compounds and to a limited number of hetercyclic derivatives containing one or two hetero atoms of one type. Chapter I is a complete survey of the interaction of nitrous acid with aromatic compounds in the presence of excess sodium nitrite. It cover the decomposition of diazonium fluoroborates to give the corresponding fluorine organic compounds. Chapter II is concerned with the theoritical discussion for the work originated in this thesis and falls in two direction : First: The interaction of antipyrine with nitrous acid in the presence of excess sodium nitrite followed by the addition of fluoroboric acid and this resulted in the formation of antipyrine-4’-diazonium fluoroborate which on pyrolysis gives 4~fluoroantipyrine.