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العنوان
Some New Approaches for the Synthesis of Azoles, Azines and Azoloazines /
المؤلف
Mekheimer, Ramadan Ahmed.
هيئة الاعداد
باحث / Ramadan Ahmed Mekheimer
مشرف / H.A.El-Fahham
مشرف / Th.Kappe
مشرف / G.H.El-Gemeie
الموضوع
Chemistry, Organic.
تاريخ النشر
1990.
عدد الصفحات
178 p.:
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
Organic Chemistry
تاريخ الإجازة
1/1/1990
مكان الإجازة
جامعة المنيا - كلية العلوم - كيمياء
الفهرس
Only 14 pages are availabe for public view

from 210

from 210

Abstract

Treatment of the hydroxyquinoline-3-carbonitriles 6a,b;24 and 29,respectively.
The 4-azidoquinoline-3-carbonitriles 8,25 and the 5-azido-tetrazolo[1,5-a]quinoline-4-carbonitriles 17a,b were prepared by reacting 6a,24 and 7a,b with sodium azide in DMF,respectively.
The phosphazenes compounds 11; 18a,b; 19and 26 were obtained ,in good yields, by reacting the corresponding azides 8; 17a,b;17a and25 with triphenylphosphine, respectively. The acid hydrolysis of these phosphzenes yielded the corresponding amines 14; 20a,b;21 and 27,respectively.
The 5-amino-tetrazolo[1,5-a]quinoline-4-carbonitrile21 is converted into 2,4-dia,ino-quinoline-4-carbonitrile 21 is converted into 2,4-diamino-quinoline-4-carbonitrile 20a by reacting it with triphenylphine to yield the intermediate 22 wich undergoes acid hydrolysis to yield 20a.