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العنوان
Polymer/ Layered Silicate Nanocomposites /
المؤلف
Bekhit, Mohamed El-Sayed El-Sayed Hassan.
هيئة الاعداد
باحث / محمد السيدالسيد حسن بخيت
مشرف / أ.د/ حماده محمد أحمد كيله
مشرف / أ.د/ زكريا اسماعيل علي
مشرف / أ.د/ حسين عامر علي يوسف
مناقش / أ.د/ حماده محمد أحمد كيله
الموضوع
Silicates - Analysis - Congresses. Polymer colloids.
تاريخ النشر
2012.
عدد الصفحات
154 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Physical and Theoretical Chemistry
تاريخ الإجازة
1/1/2012
مكان الإجازة
جامعة الزقازيق - كلية العلوم - الكيمياء
الفهرس
Only 14 pages are availabe for public view

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Abstract

Polymer–clay nanocomposites have attracted the attention of many researchers and experimental results are presented in a large number of recent papers and patents because of the outstanding mechanical properties and low gas permeabilities that are achieved in many cases. Polymer-clay nanocomposites are a new class of mineral-field polymer that contain relatively small amounts (<10%) of nanometer-sized clay particles. Polymer/clay nanocomposites have their origin in the pioneering research conducted at Toyota Central Research Laboratories and the first historical record goes back to 1987. The matrix was nylon-6 and the filler MMT. Because of its many advantages such as high mechanical properties, good gas barrier, flame retardation, etc. polymer/clay nanocomposites have been intensely investigated and is currently the subject of many research programs. Nanocomposite materials are commercially important and several types of products with different shapes and applications including food packaging films and containers, engine parts, dental materials, etc. are now available in markets. A number of synthesis routes have been developed in the recent years to prepare these materials, which include intercalation of polymers or pre-polymers from solution, in-situ polymerization, melt intercalation etc. In this study, new nanocomposite materials were produced from the components of rubber (NBR, SBR and EPDM) as the polymeric matrix and organically modified quaternary alkylammonium montmorillonite in different contents (3, 5, 7, and 10 phr) as the filler by using an extruder then, the rubber nanocomposite sheets were irradiated at adose of 0, 50, 75, 100 and150 KGy using Electron beam Irradiation technique as acrosslinking agent. These new materials can be characterized by using various analytical techniques including X-ray diffractometer XRD, Thermogravimetric analyzer TGA, scanning electron microscope (SEM), transmission electron microscope (TEM),Fourier transform infrared spectrometer (FTIR) as will as mechanical properties measurements.