الفهرس | Only 14 pages are availabe for public view |
Abstract This work targets the investigation of the potentiality of using sorghum stalks (SS) as reinforcements for high density polyethylene (HDPE), especially for outdoor applications. Characterisation of sorghum stalks was performed taking into consideration morphological, thermal, chemical, and mechanical properties, to study the potentiality of their use as a polymer reinforcing material. Optical and scanning electron microscopy was used to investigate the morphology of sorghum stalks, and relate mechanical properties to structure. Sorghum stalks have been divided into three equal regions: bottom, middle, and top, and each region was individually studied. The thermal degradation behaviour has been studied using static and dynamic thermogravimetric analysis. The results of this study show that it is not recommended to subject the fibres to elevated temperatures (>200°C) for time periods exceeding 10 min. Tensile testing was used to evaluate the mechanical properties of fibres. The highest tensile strength of 280 N/mm was found at the middle region of the sorghum stalk rind (SSR), while the tensile strength of the pith was found to be about 1.5 N/mm v 2 . After compounding SSR with HDPE and MAPE, number- 2 weighted distributions for fibre length and aspect ratio were built showing a right skewed distribution with large number of small particles. The obtained fibre length and aspect ratio distributions were fitted by a two-parameter Weibull model. With respect to the composite, mechanical properties in tension and bending were evaluated for different compositions of SSR and maleic anhydride polyethylene (MAPE) as a coupling agent. Compared to pure HDPE, 20wt% SSR/3wt% MAPE composition showed an increase of about 14%, 71%, and 156% in tensile strength, bending strength, and flexural modulus, respectively. 40wt% SSR/0wt% MAPE composition showed an increase about of 346% in flexural modulus. The resistance to the deteriorating effect of service conditions as in outdoor applications was also studied. Specimens immersed in distilled water, showed a maximum increase in weight by 6.88% at 40wt% SSR/0wt% MAPE composition. After saturation, specimens were tested in bending to compare results with un-aged specimens. A reduction in strength and modulus was found. The mechanical properties in bending of ultraviolet exposed specimens were compared to un-aged and to pure HDPE specimens. There is no significant reduction in mechanical properties compared to unexposed specimens. |