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العنوان
Advanced Studies In The Chemistry Of 2-Pyrones And Pyridones /
المؤلف
Aboulela, Salah Loutfi.
هيئة الاعداد
مشرف / قدرى مرجان
مشرف / محمد مشرقى
مشرف / ايهاب الخولى
باحث / صلاح لطفى ابو العلا
الموضوع
Chemistry Pyrones Pyridones.
تاريخ النشر
1986.
عدد الصفحات
171 p. :
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
الكيمياء
تاريخ الإجازة
1/1/1986
مكان الإجازة
جامعة الاسكندريه - كلية العلوم - Chemistry
الفهرس
Only 14 pages are availabe for public view

from 171

from 171

Abstract

The first chapter is the introduction which comprises
a review of the recent contributions in the chemistry of 2H-pyran-2-ones. The most important methods for the synthe- sis of these compounds, their reactions as well as their spectral properties were considered. In addition, this chapter also contains a concise account on the chemistry of 2-pyridones.
The second chapter is devoted to a discussion of the original work of the candidate. The condensations of phenylpropiolic esters with deoxybenzoin under different conditions were studied. Depending upon the reaction condi- tions, the above condensations gave a mixture of 4,5,6-tri- phenyl-2H-pyran-2-one (19) and 4,5,6-triphenyl-6-alkoxy- 3,6-dihydropyran-2-one (20). The structure of the dihydro- pyrans were fully established by studying their different spectral properties including infrared, 1H nmr and mass spectra. A mechanism for the above reactions was postulated.