الفهرس | Only 14 pages are availabe for public view |
Abstract Crude oil and other petroleum products are crucial to the global economy today due to increasing energy demand approximately (~1.5%) per year and significant oil remaining after primary and secondary oil recovery (~45-55% of original oil in place, OOIP), which accelerates the development of enhanced oil recovery (EOR) technologies to maximize the recovered oil amount by non-conventional methods. Polymer flooding through hydrophobically associated polyacrylamides (HAPAM) is a widely implemented EOR-technique to maximize recovered oil amount, so they attracted much attention on both academic and industrial laboratories for polymer flooding in enhanced oil recovery applications. These polymers class synthesized by grafting or incorporating hydrophobic chain cross-linking segments onto their hydrophilic main chain. In this study, the authors reported about synthesis of polymeric surfmer (surface-active monomers) which have amphiphilic structure with polymerizable vinyl double bonds in the molecular structure resulting in novel properties distinct from conventional surfactants. Hydrophobically associating polyacrylamide (HAPAM) prepared by free radical emulsion polymerization of acrylamide (AM) monomer, divinyl sulfone as hydrophobic crosslinked moiety and surfmers, to chemically anchor a surfmer and hydrophobic crosslinker moiety onto the back bone of acrylamide chain. After that, polymeric nanocomposite was prepared through copolymerization of prepared HAPAM with different molar ratios of silica nanoparticles through one shot synthesis. The effects of initiator concentration, monomer concentration, silica concentration, cross linker concentration, surfmers concentration and reaction temperature on apparent viscosity of the product were determined using single- factor and orthogonal experiments. |