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العنوان
Preparation and characterization of
Nanopolymeric Particles using Polymerizable Surfactants for Rock Wettability Alteration
and Oil Production Improvement \
الناشر
Abd el Aziz Nasr Moawed Bakr El-hoshoudy ,
المؤلف
El-hoshoudy,Abd el Aziz Nasr Moawed Bakr .
هيئة الاعداد
مشرف / Mohammed Youssif El-Kady
مشرف / Saad El-Din Mohammed Desouky
الموضوع
Chemistry .
تاريخ النشر
2015 .
عدد الصفحات
192p. :
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
Inorganic Chemistry
الناشر
Abd el Aziz Nasr Moawed Bakr El-hoshoudy ,
تاريخ الإجازة
1/1/2015
مكان الإجازة
جامعة أسيوط - كلية العلوم - Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

Crude oil and other petroleum products are crucial to the global
economy today due to increasing energy demand approximately (~1.5%)
per year and significant oil remaining after primary and secondary oil
recovery (~45-55% of original oil in place, OOIP), which accelerates the
development of enhanced oil recovery (EOR) technologies to maximize
the recovered oil amount by non-conventional methods. Polymer flooding
through hydrophobically associated polyacrylamides (HAPAM) is a
widely implemented EOR-technique to maximize recovered oil amount, so they attracted much attention on both academic and industrial laboratories for polymer flooding in enhanced oil recovery applications. These polymers class synthesized by grafting or incorporating hydrophobic chain cross-linking segments onto their hydrophilic main chain.
In this study, the authors reported about synthesis of polymeric surfmer
(surface-active monomers) which have amphiphilic structure with polymerizable
vinyl double bonds in the molecular structure resulting in novel properties
distinct from conventional surfactants. Hydrophobically associating
polyacrylamide (HAPAM) prepared by free radical emulsion polymerization of
acrylamide (AM) monomer, divinyl sulfone as hydrophobic crosslinked moiety
and surfmers, to chemically anchor a surfmer and hydrophobic crosslinker
moiety onto the back bone of acrylamide chain. After that, polymeric
nanocomposite was prepared through copolymerization of prepared HAPAM
with different molar ratios of silica nanoparticles through one shot synthesis.
The effects of initiator concentration, monomer concentration, silica
concentration, cross linker concentration, surfmers concentration and reaction
temperature on apparent viscosity of the product were determined using single-
factor and orthogonal experiments.