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العنوان
Sally Gamal Sedeek \
المؤلف
Saleh,Sally Gamal Sedeek .
هيئة الاعداد
مشرف / سالى جمال صديق صالح
مشرف / محمد محمود محمد ابو على
مشرف / . بدر الدين عواد السيد محمد
مشرف / دينا يحيى صبرى
تاريخ النشر
2015.
عدد الصفحات
113p.;
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الكيمياء
تاريخ الإجازة
1/1/2015
مكان الإجازة
جامعة عين شمس - كلية العلوم - الكمياء
الفهرس
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Abstract

Azomethines are nitrogen-based 1,3- dipoles, consisting of an iminium ion next to a carbanion. They are used as ligands which are able to coordinate metal through imine nitrogen and another group, usually linked to carbonyl group. In fact, azomethine ligands are able to coordinate many different metals and to stabilize them in various oxidation states. They have been widely studied because of their application in many fields of fundamental and applied research. A number of azomethine used for the qualitative analysis, quantitive analysis [Kalaskar et. al, 2013]. Azomethine imines are used as intermediate in synthetic organic chemistry [Schantl et. al, 2004].
[Ashley et. al, 2013] have been synthesized azomethine imines using an intramolecular alkyene hydrohydrazation approach. They have been noted the increased reactivity associated with the use of 3,5 – bis (trifluoromethyl) benzhydrazides [Loiseau et. al, 2011]. They also speculated that the bis (trifluoromethyl) benzoyl group would stabilize the negative charge of the dipole sufficiently to allow isolation of azomethine imines from appropriate precursors as shown in Table (1).