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العنوان
Synthesis of some heterocyclic compounds via microwave irradiation techniques /
المؤلف
Kamel, Moumen Samir.
هيئة الاعداد
باحث / مؤمن سمير كامل
مشرف / فتحي فهيم عبد اللطيف
مشرف / محمد عبد الله أمين
الموضوع
Heterocyclic compounds.
تاريخ النشر
2016.
عدد الصفحات
127 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Organic Chemistry
تاريخ الإجازة
1/6/2016
مكان الإجازة
جامعة المنيا - كلية العلوم - الكيمياء
الفهرس
Only 14 pages are availabe for public view

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Abstract

The present study was planned for the synthesis of some new spiropyran using microwave irradiation. The starting material 1H-indole-2,3-dione (isatin) 371a,b or Indol-3-carbaldehyde was reacted with malononitrile (372), and/or acetylacetone, ethyl acetoacetate, dimedone, cyclopentanone, cyclohexanone, cycloheptanone, barbituric acid, 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one and rhodanine or some phenols namely; hydroquinone, catechol or pyrogallol using diammonium hydrogen phosphate (DAHP) as a catalyst in aqueous ethanol (H2O∕EtOH) in microwave (180 watts) for 4 minutes afforded the corresponding pyran derivatives.
And reaction of 1H-indole-2,3-dione (isatin) 371a,b with malononitrile (372), and/or some phenols namely; phenol, resorcinol, 4-chlororesorcinol, 1-naphthol, catechol, 1,5-dihydroxy naphthalene or 2,7-dihydroxynaphthalene in saturated solution of K2CO3 in microwave (360 watts) for 4 minutes afforded the corresponding pyran derivatives.