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العنوان
Synthesis of some pyridine derivatives and study the
effect of humic acid on the adsorption of these
compounds onto nano-clay.
المؤلف
Abdel-Raheem,Shaban Ahmed Ali.
هيئة الاعداد
باحث / Shaban Ahmed Ali Abdel-Raheem
مشرف / Adel M. K. El-Dean
مشرف / Reda Hassanien Mohamed
مشرف / Aly Ahmed Abd-Ella
مشرف / Mohamed E. A. Elsayed
مناقش / Mohamed Hassan Abdet-Rehim Hassan
مناقش / Osama Shehata lVlostafa Ali
مناقش / Ader Mohamed Kamar Er-Dean
مناقش / Reda Hassanien Mohamed
مناقش / Aly Ahmed Abd-Ella
تاريخ النشر
2019
عدد الصفحات
335 p.:
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
الكيمياء
الناشر
تاريخ الإجازة
31/12/2019
مكان الإجازة
جامعة الوادى الجديد - كلية العلوم - الكيمياء
الفهرس
Only 14 pages are availabe for public view

from 335

from 335

Abstract

The present work was planned to synthesize some new
pyridine derivatives and to study the insecticidal activities of
them against Cowpea Aphid, Aphis craccivora Koch
(Homoptera: Aphididae). Also, the effect of humic acid on the
adsorption of a promising insecticide onto bentonite nanocaly
was evaluated The synthesis of the target compounds started from
malononitrile which on reaction with acetylacetone afforded 3-
cyano-4,6-dimethylpyridin-2(1H)-one (I) that undergo
chlorination with POCl3 to give 2-chloro-3-cyano-4,6-
dimethylpyridine (II). The compound 3-cyano-4,6-
dimethylpyridin-2(1H)-thione (III) was obtained by reaction of
chloro compound (II) with thiourea. Condensation of compound
(III) with benzaldehyde in the presence of few drops of
piperidine resulted in the formation of 3-cyano-4,6-
distyrylpyridin-2(1H)-thione (IV).