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العنوان
Preparation, spectral characterization and theoretical studies of some transition metal complexes with Schiff bases /
الناشر
Yasmin Mamdoh Hussien Ahmed ,
المؤلف
Yasmin Mamdoh Hussien Ahmed
هيئة الاعداد
باحث / Yasmin Mamdoh Hussien Ahmed
مشرف / Walaa Hamed Mahmoud
مشرف / Yasmin Mamdoh Hussien Ahmed
مناقش / Hyman Hassan Rehan
تاريخ النشر
2018
عدد الصفحات
161 P. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Inorganic Chemistry
تاريخ الإجازة
28/9/2018
مكان الإجازة
جامعة القاهرة - كلية العلوم - Inorganic Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

Two novel Schiff bases of [1-(5-(1-((8-aminonaphthalen-1-yl)imino)ethyl)-2,4-dihydroxyphenyl)ethanone] (H₂L¹ ) , 1-(2,4-dihydroxy-5-(1-((4-methylthiazol-2-yl)imino)ethyl)phenyl)ethanone (H₂L²), and their complexes with Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) were prepared and subjected to many analytical techniques such as elemental analyses, mass spectroscopy, IR, ¹H NMR, magnetic moment, molar conductance and thermal analyses techniques (TG ). The chelates were found to have octahedral geometry except Cr(III)-H2L2 which has distorted square planar geometry. The biological activity (antimicrobial and antibreastic cancer activity) of the ligands and their complexes were also screened