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العنوان
Electrochemical sensors based on sensitive composites for determination of some organic compounds /
الناشر
Nada Abdalnasser Mohamed Ahmed ,
المؤلف
Nada Abdalnasser Mohamed Ahmed
هيئة الاعداد
باحث / Nada Abdalnasser Mohamed Ahmed
مشرف / Nada F. Atta
مشرف / Ekram Hamdy Elsayed
مناقش / Ekram Hamdy Elsayed
تاريخ النشر
2018
عدد الصفحات
84 P. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Physical and Theoretical Chemistry
تاريخ الإجازة
23/5/2019
مكان الإجازة
جامعة القاهرة - كلية العلوم - Physical Chemistry
الفهرس
Only 14 pages are availabe for public view

from 134

from 134

Abstract

Effective electrochemical sensors, based on ionic liquid crystal (ILC) and NdFeO3 nano-perovskite (NF)/ILC modified carbon paste electrode (CP), were introduced for the electrochemical determination of di-hydroxybenzene isomers exhibiting higher electro-catalytic activity compared to unmodified electrodes. ILCCP and NFILCCP were utilized for the electrochemical sensing of hydroquinone (HQ) and catechol (CC) in the presence of sodium dodecyl sulfate (SDS). The effect of type of ionic liquid and the amounts of ILC, NdFeO3 and SDS have been studied and optimized. NdFeO3 nano-perovskite has been prepared via citrate-nitrate microwave assisted combustion method. The characterization of the prepared nano-perovskite, morphological and structural identification, was done using XRD, SEM, EDAX, FTIR and TEM techniques. NdFeO3 and ILC were used as modifiers in the CP and SDS as a preconcentrating agent. In general, the proposed sensors exhibited superior performance toward the determination of the studied compounds in terms of selectivity, wide linearity range, sensitivity, low detection limits, applicability in real samples, good stability and anti-interference ability