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العنوان
Electrochemical preparation and characterization of tungsten oxide based-photoanodes for solar fuel cell /
الناشر
Aya Maher Mohamed Mohamed ,
المؤلف
Aya Maher Mohamed Mohamed
هيئة الاعداد
باحث / Aya Maher Mohamed Mohamed
مشرف / Bahgat E. Elanadouli
مشرف / Nageh Khalaf Allam
مشرف / Mohamed Saada Eldeab
تاريخ النشر
2016
عدد الصفحات
108 P. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Physical and Theoretical Chemistry
تاريخ الإجازة
29/4/2017
مكان الإجازة
جامعة القاهرة - كلية العلوم - Physical Chemistry
الفهرس
Only 14 pages are availabe for public view

from 154

from 154

Abstract

Nanoporous and nanoflakes tungsten oxide (WO) based photoanodes 3 were produced via one step anodization method. The effect of annealing temperature on the morphological, structural and optical properties was studied. Photoelectrochemical activity test reveals that nanoflakes annealed at 500oC exhibited a superior photocatalytic performance among the other samples. In the second part of the thesis, an electrochemical method is proposed to study the nature of the defect states inside promising sub-stoichiometric tungsten oxide nanoflake via annealing under different streams of gases. Optical, structural and PEC characterization confirmed the presence of defect states (oxygen vacancies). A defect sensitivity factor is proposed and used to indicate whether defect states in each electrode are mostly deep or shallow in nature