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Abstract Synthetic (SrTiO₃) has a very large dielectric constant at room temperature and low electric field. Aiming to increase the dielectric constant of PVDF, a different amount of SrTiO₃ are added to it. A correlation between structural changes and the physical properties of these composites was elucidated. The effect of doping with SrTiO₃ on electrical conductionin PVDF was undertaken. The effect of SrTiO₃ doping in PVDF on the dc electrical properties as well as the electrical conduction mechanisms was studied. The dielectric properties of PVDF as a function of SrTiO₃ doping and both temperature and applied frequency was elucidated. Finally, the structural changes in PVDF matrix owing to SrTiO₃ doping via IR and XRD spectroscopy was presented |