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العنوان
Synthesis and Photophysical Properties of Some New 2(3H)-Furanone Derivatives /
المؤلف
Aly, Asmaa Samir Fathy.
هيئة الاعداد
باحث / أسماء سمير فتحى على
مشرف / سحر سعيد السقا
مشرف / رشا مصطفى كامل
مشرف / محمد حلمى عبدالحميد سليمان
مناقش / السيد حسين مصطفى الطمنى
مناقش / وليد فتح الله محمد
الموضوع
2(3H)-Furanone Derivatives. N-acylhydrazones.
تاريخ النشر
2023.
عدد الصفحات
i-v, 158 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Organic Chemistry
الناشر
تاريخ الإجازة
1/1/2023
مكان الإجازة
جامعة السويس - المكتبة المركزية - الكيمياء
الفهرس
Only 14 pages are availabe for public view

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Abstract

In the present study, 5-aryl-3-((E)-3-phenylallylidene)-2(3H)-furanones (3a-f) were synthesized then allowed to react with hydrazine hydrate gave the corresponding hydrazides (4a-c). the reaction of the hydrazides with aromatic aldehydes in refluxing benzene or ethanol gave the corresponding N’-((E) arylidene)-2-(2-oxo-2-arylethyl)-5-phenylpenta-2,4-diene hydrazide (5a-i) or 5 aryl-1-arylidenamino-3-((E)-3-phenylallylidene)-1,3-dihydro-2(3H)-pyrrolone (6a i) respectively. On refluxing the hydrazides in benzene 5-styryl-1,2-dihydro-3 pyrazolones is generated (7a-b). On the other hand, refluxing the hydrazides (4b) in ethanol 1-amino-5-(4-chlorophenyl)-3-(3-phenylallylidene)-1,3-dihydro-2H pyrrol-2-one is produced. The structures of the synthesized compounds were confirmed by spectral data (IR,H1NMR and Mass Spectroscopy).The photophysical properties of furanone derivatives such as UV, Fluorescence, stock shift and quantum yield were studied.