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العنوان
Removal of organic pollutants from industrial waste water by electrochemical techniques /
الناشر
Yasmin Ossama Ahmed Fouad ,
المؤلف
Fouad, Yasmin Ossama Ahmed
هيئة الاعداد
باحث / ياسمين أسامة أحمد فؤاد
مشرف / حسن عبد المنعم فرج
مشرف / عبد العزيز حسانين قنصوة
مناقش / يحيى عبد القادر الطويل
مناقش / ألفت عبد الشافى فضالى
الموضوع
Organic chemistry . Electrochemistry Chemical engineering .
تاريخ النشر
2005 .
عدد الصفحات
188 P .:
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الهندسة (متفرقات)
تاريخ الإجازة
1/1/2005
مكان الإجازة
جامعة الاسكندريه - كلية الهندسة - الهندسة الكيميائية
الفهرس
Only 14 pages are availabe for public view

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Abstract

The present work deals with the removal of finely dispersed oil from oil/water emulsions by electrocoagulation using an electrolytic cell with horizontal Al electrodes. Sepatartion efficiency and rate of separation were studied under different conditions of the following variables: 1-. Current density. 2-Temperature. 3- Emulsion pH. 4- Electrolyte (NaC1) concentration. 5- Electrode Dimensions (anode cylinder diameter). 6- Electrode orientation (horizontal vs. vertical). The study revealed the following results: 1- The present work has shown that the performance of a cell with horizontally oriented electrodes is superior to the traditional vertical electrode cell in conducting electrocoagulation of emulsions. Indicators used to measure the cell performance were; separation efficiency, the rate constant of the demulsification process and the time required to reduce the oil content in the emulsion by 50% (t05). Separation efficiencies up to 99.9% were obtained which reduces the oil content in water to the safe level specified by the American EPA in a reasonable time. 2- The present results have shown that the electrocoagulation is an efficient way for treating oil-water emulsions where the oil content can be decreased below the permissible value. However, with sea water, a considcrablc demulsification takes place but the final oil concentration was above the maximum permissible value. i.e., in case of sea water electrocoagulation can be used in conjunction with another method such as ultrafiltration to demulsify completely oil-sea water emulsions.