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العنوان
Synthesis, biological evaluation and industrial application of some new heterocyclic compounds containing nitrogen and / or sulfur /
المؤلف
Al-Nakeeb, Azah Qaid Saif Mansoor.
هيئة الاعداد
مشرف / عزة قائد سيف منصورالنقيب
مشرف / أحمد على حامد فضة
مشرف / محمد أحمد اسماعيل أبو العينين
مشرف / محمد رمضان أحمد المرسي
مناقش / ياسر عبدالعال سليم
مناقش / اسلام رضا عبدالسيد الصاوي
الموضوع
Organic Chemistry.
تاريخ النشر
2023.
عدد الصفحات
305 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Organic Chemistry
تاريخ الإجازة
01/01/2023
مكان الإجازة
جامعة المنصورة - كلية العلوم - قسم الكيمياء العضوية
الفهرس
Only 14 pages are availabe for public view

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from 305

Abstract

In this thesis, we have synthesized new heterocyclic compounds for industrial application and biological evaluations. The thesis is divided in to two parts as follow: Part I: Efficient co-sensitization of novel trimethoxybenzene-based dyes with N-719 for highly efficient dye-sensitized solar cells We have synthesized different trimethoxybenzene based heterocyclic compound AL1-5 for DSSCs application. Their chemical structures were confirmed by the different elemental and spectral analysis. Moreover, from their UV spectra, all dyes showed high molar extinction co-efficient which attributed to the incorporation of trimethoxybenzene moiety and cyanoacetanilides derivatives as strong acceptor moiety beside the superior donating power of the trimethoxybenzene. Further, DFT / TD-DFT studies was performed using Gaussian 09 to gain inside the molecular structure of the new dyes besides measuring HOMO / LUMO energy levels. Scheme 1 showed the synthetic pathway of five novel D-π-A configured metal free dyes AL1-5 possessing trimethoxybenzene moiety as a strong donating moiety. The target dyes AL1-5 were obtained in good yield.